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Two-dimensional confinement for generating thin single crystals for applications in time-resolved electron diffraction and spectroscopy: an intramolecular proton transfer study

authors
Hyein Hwang, Vandana Tiwari, Hong-Guang Duan, Simon F. Bittmann, Friedjof Tellkamp, Ajay Jha and R. J. Dwayne Miller
date published
Aug. 3, 2022
journal
Chemical Communications
publisher
Royal Society of Chemistry
volume, number
58
pages
9774-9777
doi
https://doi.org/10.1039/D2CC02468C
abstract

Thin single organic crystals (≤1 μm) with large area (≥100 × 100 μm2) are desirable to explore photoinduced processes using ultrafast spectroscopy and electron-diffraction. Here, we present a general method based on spatial confinement to grow such crystals using the prototypical proton transfer system, 1,5-dihydroxyanthraquinone, as an example, and provide the protocol for optically characterizing structural dynamics to enable proper assignments using diffraction methods.